MODE SPECIFIC PHOTODISSOCIATION OF THE B-1(2) STATE OF CS2

被引：20

作者：

STARRS, C ^{[1
]}

JEGO, MN ^{[1
]}

MANK, A ^{[1
]}

HEPBURN, JW ^{[1
]}

机构：

[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 16期

关键词：

D O I：

10.1021/j100195a004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report results on the dynamics and spectroscopy of the predissociating B-1(2) state of CS2, excited at wavelengths around 200 nm. The atomic S product electronic state branching ratio is a strong function of which band in the B-1(2)(1-SIGMA+u) <-- X1-SIGMA+g system is pumped. K = 0 bands lead to mostly S(P-3(2)) products, while K = 1 bands produce MUCh less S(P-3(2)) and show a marked enhancement of S(1D2).

引用

页码：6526 / 6529

页数：4

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