X-RAY PHOTOELECTRON-SPECTRA OF POLYHYDRIDO COMPLEXES OF TUNGSTEN AND MOLYBDENUM

被引：14

作者：

SHULGA, YM ^{[1
]}

PIVOVAROV, AP ^{[1
]}

MAKHAEV, VD ^{[1
]}

BORISOV, AP ^{[1
]}

机构：

[1] ACAD SCI USSR,INST NEW CHEM PROBLEMS,CHERNOGOLOVKA,USSR

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)83119-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

X-Ray photoelectron spectroscopy has been applied to study MH4L4(M = or Mo, L = PHPh2, PMePh2, PEtPh2, PBuPh2, PEt2Ph, P(OPr-i)3 or 1 2 dppe). It has been shown that tungsten in these compounds has a negative charge whereas the charge of molybdenum is almost zero. © 1979.

引用

页码：47 / 50

页数：4

共 12 条

[1] ARESTA M, 1972, GAZZ CHIM ITAL, V102, P755
[2] BILLOEN P, 1973, J CATAL, V30, P169
[3] BORISOV AP, 1978, COORD CHEM USSR, V4, P1274
[4] REACTIONS OF TETRAHYDRIDOTETRAKIS(METHYLDIPHENYLPHOSPHINE) MOLYBDENUM(IV) AND TUNGSTEN (IV) WITH ACIDS
CARMONAGUZMAN, E
WILKINSON, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (18): : 1716 - 1721
[5] ELECTRONIC-STRUCTURE OF TUNGSTEN AND SOME OF ITS BORIDES, CARBIDES, NITRIDES, AND OXIDES BY X-RAY ELECTRON-SPECTROSCOPY
COLTON, RJ
RABALAIS, JW
[J]. INORGANIC CHEMISTRY, 1976, 15 (01) : 236 - 238
[6] ELECTRON SPECTROSCOPY OF PLATINUM COMPLEXES
COOK, CD
WAN, KY
GELIUS, U
HAMRIN, K
JOHANSSO.G
OLSSON, E
SIEGBAHN, H
NORDLING, C
SIEGBAHN, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (08) : 1904 - &
[7] KINETICS AND MECHANISM OF REDUCTION OF VIB TRANSITION-METAL OXIDES AND THEIR OXYSALTS
HABER, J
[J]. JOURNAL OF THE LESS-COMMON METALS, 1977, 54 (01): : 243 - 261
[8] LARSSON R, 1976, CHEM SCRIPTA, V9, P148
[9] PENNELLA F, 1971, J CHEM SOC CHEM COMM, P158
[10] SEMENENKO KN, 1978, COORD CHEM USSR, V4, P146

← 1 2 →