BREAKTHROUGH CURVE OF LYSINE ON A COLUMN OF A STRONG CATION-EXCHANGE RESIN OF THE AMMONIUM FORM

被引:6
|
作者
KAWAKITA, T
ITO, Y
SANO, C
OGURA, T
SAEKI, M
机构
[1] AJINOMOTO CO INC,KAWASAKI FACTORY,DEPT PROD,KAWASAKI KU,KAWASAKI,KANAGAWA 210,JAPAN
[2] AJINOMOTO CO INC,CTR TECHNOL & ENGN,KAWASAKI KU,KAWASAKI,KANAGAWA 210,JAPAN
[3] AJINOMOTO CO INC,KYUSHU FACTORY,DEPT PROD,SAGA 84021,JAPAN
关键词
D O I
10.1080/01496399108049904
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By using a "finite-segment" model for an ion-exchange column, breakthrough curves of ternary cation components - lysine, ammonium, and hydrogen - on a column of a cation-exchange resin of the ammonium form are calculated as a function of limited parameters such as the selectivity coefficients and the dissociation constant of the amino acid. Experimental breakthrough curves on a fixed column packed with Diaion SK-IB (nominal DVB 8%) are simulated and analyzed by the calculated results. Within a limited flow rate of the liquid phase, the model is valid for experimental results, including dependencies on the pH and the ratio of lysine to ammonium, when the conditions of electroneutrality are obeyed.
引用
收藏
页码:619 / 635
页数:17
相关论文
共 50 条
  • [41] INDOMETHACIN AND CATION-EXCHANGE RESIN IN THE MANAGEMENT OF PSEUDOHYPOALDOSTERONISM
    MATHEW, PM
    MANASRA, KB
    HAMDAN, JA
    CLINICAL PEDIATRICS, 1993, 32 (01) : 58 - 60
  • [42] NOVEL WEAK ACID CATION-EXCHANGE COLUMN
    JENSEN, D
    WEISS, J
    REY, MA
    POHL, CA
    JOURNAL OF CHROMATOGRAPHY, 1993, 640 (1-2): : 65 - 71
  • [43] Polymeric strong cation-exchange monolithic column for capillary liquid chromatography of peptides and proteins
    Chen, Xin
    Tolley, H. Dennis
    Lee, Milton L.
    JOURNAL OF SEPARATION SCIENCE, 2009, 32 (15-16) : 2565 - 2573
  • [44] REACTIONS OF MERCURY(II) WITH A CATION-EXCHANGE RESIN
    WALTON, HF
    MARTINEZ, JM
    JOURNAL OF PHYSICAL CHEMISTRY, 1959, 63 (08): : 1318 - 1319
  • [45] HYDROLYSIS OF SEVERAL PURINE NUCLEOSIDES WITH STRONG HYDROCHLORIC-ACID OR CATION-EXCHANGE RESIN
    SUZUKI, Y
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1974, 47 (08) : 2077 - 2078
  • [46] KINETICS OF AN ESTERIFICATION WITH CATION-EXCHANGE RESIN CATALYST
    LEVESQUE, CL
    CRAIG, AM
    INDUSTRIAL AND ENGINEERING CHEMISTRY, 1948, 40 (01): : 96 - 99
  • [47] Preparation of monolithic silica column with strong cation-exchange stationary phase for capillary electrochromatography
    Xie, CH
    Hu, JW
    Xiao, H
    Su, XY
    Dong, J
    Tian, RJ
    He, ZK
    Zou, HF
    JOURNAL OF SEPARATION SCIENCE, 2005, 28 (08) : 751 - 756
  • [48] Capillary trap column with strong cation-exchange monolith for automated shotgun proteome analysis
    Wang, Fangjun
    Dong, Jing
    Jiang, Xiaogang
    Ye, Mingliang
    Zou, Hanfa
    ANALYTICAL CHEMISTRY, 2007, 79 (17) : 6599 - 6606
  • [49] EFFECT OF CATION-EXCHANGE RESIN IN THE PREPARATION OF PHENOLPHTHALEIN
    JOAG, NG
    KALE, DD
    INDIAN JOURNAL OF TECHNOLOGY, 1988, 26 (10): : 491 - 494
  • [50] STUDIES OF CATION-EXCHANGE EQUILIBRIUM ON A SYNTHETIC RESIN
    LOWEN, WK
    STOENNER, RW
    ARGERSINGER, WJ
    DAVIDSON, AW
    HUMEDN
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (06) : 2666 - 2674