BREAKTHROUGH CURVE OF LYSINE ON A COLUMN OF A STRONG CATION-EXCHANGE RESIN OF THE AMMONIUM FORM

被引:6
|
作者
KAWAKITA, T
ITO, Y
SANO, C
OGURA, T
SAEKI, M
机构
[1] AJINOMOTO CO INC,KAWASAKI FACTORY,DEPT PROD,KAWASAKI KU,KAWASAKI,KANAGAWA 210,JAPAN
[2] AJINOMOTO CO INC,CTR TECHNOL & ENGN,KAWASAKI KU,KAWASAKI,KANAGAWA 210,JAPAN
[3] AJINOMOTO CO INC,KYUSHU FACTORY,DEPT PROD,SAGA 84021,JAPAN
关键词
D O I
10.1080/01496399108049904
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By using a "finite-segment" model for an ion-exchange column, breakthrough curves of ternary cation components - lysine, ammonium, and hydrogen - on a column of a cation-exchange resin of the ammonium form are calculated as a function of limited parameters such as the selectivity coefficients and the dissociation constant of the amino acid. Experimental breakthrough curves on a fixed column packed with Diaion SK-IB (nominal DVB 8%) are simulated and analyzed by the calculated results. Within a limited flow rate of the liquid phase, the model is valid for experimental results, including dependencies on the pH and the ratio of lysine to ammonium, when the conditions of electroneutrality are obeyed.
引用
收藏
页码:619 / 635
页数:17
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