FATTY-ACIDS .54. SOME REACTIONS OF LONG-CHAIN OXYGENATED ACIDS WITH SPECIAL REFERENCE TO THOSE FURNISHING FURANOID ACIDS

被引：21

作者：

GUNSTONE, FD

WIJESUNDERA, RC

机构：

[1] Department of Chemistry, The University of St. Andrews, Scotland KY16 9ST, The Purdie Building

来源：

CHEMISTRY AND PHYSICS OF LIPIDS | 1979年 / 24卷 / 02期

关键词：

D O I：

10.1016/0009-3084(79)90088-4

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

C18 furanoid acids are prepared from natural oxygenated acids by palladium (II)-catalysed cyclodehydrogenation, by rearrangement of epoxides with iodopropane-sodium iodide-dimethylsulphoxide, and by dehydration of endoperoxides. Some reactions give mixed products but routes to the individual 10,13-, 9,12- and 8,11-furans are reported. The endoperoxide route leads to speculation about the biosynthesis of natural furanoid acids. © 1979.

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页码：193 / 208

页数：16

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