REDUCTIVE DECYANATION OF ALPHA-CYANO AND ALPHA-ALKOXYCARBONYL SUBSTITUTED NITRILES PROMOTED BY SAMARIUM(II) IODIDE

被引：35
作者：
KANG, HY
HONG, WS
CHO, YS
KOH, HY
机构：
[1] KOREA INST SCI & TECHNOL, DIV APPL SCI, SEOUL 130650, SOUTH KOREA
[2] CHUNGBUK NATL UNIV, DEPT CHEM, CHONJU 360763, SOUTH KOREA
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 42期
关键词：
D O I：
10.1016/0040-4039(95)01606-I
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Decyanation of geminal dinitriles and alpha-alkoxycarbonyl substituted nitriles promoted by samarium(II) iodide has been efficiently achieved. This method has advantages over the previously known radical route using tin hydride with respect to applicable substrates and the reaction temperature employed. This decyanation could broaden the synthetic applicability of the nitrile derivatives.
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页码：7661 / 7664
页数：4
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