HARD/SOFT INTERACTIONS IN EARLY TRANSITION-METAL THIOETHER MACROCYCLIC CHEMISTRY - SYNTHESIS AND SINGLE-CRYSTAL STRUCTURE OF CIS-[CRCL2([14]ANES(4))PF6 ([14]ANES(4)=1,4,8,11-TETRATHIACYCLOTETRADECANE)

被引：24

作者：

CHAMPNESS, NR

JACOB, SR

REID, G

FRAMPTON, CS

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

[2] ROCHE PROD LTD,WELWYN GARDEN CIT AL7 3AY,HERTS,ENGLAND

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 01期

关键词：

D O I：

10.1021/ic00105a061

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [CrCl2([14]aneS(4))]PF6; a rare example of thioether coordination to Cr(III), has been isolated. The X-ray structure of [CrCl2([14]aneS(4))]PF6 shows the Crm ion coordinated to all four thioether donors of a folded [14]aneS(4) ligand with cis-dichloro ligands completing the distorted octahedral stereochemistry: Cr-Cl = 2.295(1) Angstrom, Cr-S = 2.393(1), 2.407(2) Angstrom.

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页码：396 / 398

页数：3

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