SOLUTE SOLVENT INTERACTIONS AND THEIR EMPIRICAL DETERMINATION BY MEANS OF SOLVATOCHROMIC DYES

被引:53
|
作者
REICHARDT, C
ASHARINFARD, S
BLUM, A
ESCHNER, M
MEHRANPOUR, AM
MILART, P
NIEM, T
SCHAFER, G
WILK, M
机构
[1] Department of Chemistry, Philipps University, Hans-Meerwein-Strasse, D-35032, Marburg
关键词
D O I
10.1351/pac199365122593
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The solvatochromism, thermochromism, piezochromism, halochromism, and potential chiro-solvatochromism of solutions of various pyridinium N-phenoxide betaine dyes have been used by us and others to study UV/Vis-spectroscopically the dye/solvent interactions in organic solvents of different polarity, different temperature, different external pressure, different electrolyte concentration, and different chirality.
引用
收藏
页码:2593 / 2601
页数:9
相关论文
共 50 条
  • [1] SOLVATOCHROMIC DYES AS EMPIRICAL INDICATORS OF SOLVENT POLARITY
    REICHARDT, C
    CHIMIA, 1991, 45 (10) : 322 - 324
  • [2] Investigations of solvent-solute interactions in room temperature ionic liquids using solvatochromic dyes
    Muldoon, Mark J.
    Gordon, Charles M.
    Dunkin, Ian R.
    Journal of the Chemical Society. Perkin Transactions 2, 2001, (04): : 433 - 435
  • [3] Investigations of solvent-solute interactions in room temperature ionic liquids using solvatochromic dyes
    Muldoon, MJ
    Gordon, CM
    Dunkin, IR
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2001, (04): : 433 - 435
  • [4] Solute-solvent interactions within aqueous poly(ethylene glycol): solvatochromic probes for empirical determination and preferential solvation
    Singh, Pallavi
    Pandey, Siddharth
    GREEN CHEMISTRY, 2007, 9 (03) : 254 - 261
  • [5] On the determination of polarity parameters of silica by means of solvatochromic probe dyes
    Spange, S
    Reuter, A
    Vilsmeier, E
    COLLOID AND POLYMER SCIENCE, 1996, 274 (01) : 59 - 69
  • [6] Solvatochromic study of 2-hydroxy-4-methylquinoline for the determination of dipole moments and solute-solvent interactions
    Rautela, R.
    Joshi, N. K.
    Joshi, H. C.
    Tewari, N.
    Pant, S.
    JOURNAL OF MOLECULAR LIQUIDS, 2010, 154 (01) : 47 - 51
  • [7] Solute-Solvent Interactions in Solutions of Solvatochromic Phenoxides: A Dynamics Simulation Study
    Mascayano, Carolina
    Caroli Rezende, Marcos
    Mendez, Carolina
    Nunez, Gabriel
    Chiang, Valeska
    JOURNAL OF SOLUTION CHEMISTRY, 2009, 38 (03) : 363 - 371
  • [8] Solute-Solvent Interactions in Solutions of Solvatochromic Phenoxides: A Dynamics Simulation Study
    Carolina Mascayano
    Marcos Caroli Rezende
    Carolina Mendez
    Gabriel Núñez
    Valeska Chiang
    Journal of Solution Chemistry, 2009, 38 : 363 - 371
  • [9] NEW EMPIRICAL PARAMETRIZATION OF SOLUTE-SOLVENT INTERACTIONS
    DANCE, I
    MILLER, TR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, (169): : 66 - 66
  • [10] Determination of empirical polarity parameters of the cellulose solvent N,N-dimethylacetamide/LiCl by means of the solvatochromic technique
    Spange, S
    Reuter, A
    Vilsmeier, E
    Heinze, T
    Keutel, D
    Linert, W
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1998, 36 (11) : 1945 - 1955