REDUCTIVE REMOVAL BY SODIUM BOROHYDRIDE OF SIDE-CHAIN OXYGEN FROM PHENOLIC KETONES

被引：29

作者：

BELL, KH

机构：

[1] Department of Chemistry, University of Newcastle, NSW

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 03期

关键词：

D O I：

10.1071/CH9690601

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of a variety of phenolic carbonyl compounds with boiling aqueous alkaline sodium borohydride has been studied. When the carbonyl group is ortho or para to a phenolic hydroxyl, reduction proceeds to the methylene derivative, but stops at the carbinol stage when the phenolic hydroxyl and carbonyl group are meta oriented. The simplicity and selectivity of the reaction makes it of synthetic value. © 1969, CSIRO. All rights reserved.

引用

页码：601 / &

共 8 条

[1] SELECTIVE REDUCTIONS .11. REACTION OF SODIUM BOROHYDRIDE WITH ALKYL HALIDES UNDER SOLVOLYTIC CONDITIONS . BOROHYDRIDE AS A CONVENIENT TRAP FOR CARBONIUM IONS [J].