ASYMMETRIC-SYNTHESIS OF BIARYLS BY INTRAMOLECULAR OXIDATIVE COUPLINGS OF CYANOCUPRATE INTERMEDIATES

被引：134

作者：

LIPSHUTZ, BH

KAYSER, F

LIU, ZP

机构：

[1] Department of Chemistry, University of California, Santa Barbara, California

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 18期

关键词：

D O I：

10.1002/anie.199418421

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With a judicious choice of tether from the “chiral pool”, coupling of the two aryl rings in nonracemic 1 yields only one of the two possible diastereomers of biaryl 2. G  C or O substituent; R, R′  H, 3OMe. This method is expected to be widely applicable. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：1842 / 1844

页数：3

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