N-TYPE DOPING PROPERTIES AND ELECTRONIC STATES OF POLY(2,5-THIENYLENE VINYLENE)

被引：16

作者：

ONODA, M ^{[1
]}

MORITA, S ^{[1
]}

IWASA, T ^{[1
]}

NAKAYAMA, H ^{[1
]}

YOSHINO, K ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT ELECTR ENGN,2-1 YAMADA OKA,SUITA,OSAKA 565,JAPAN

来源：

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1992年 / 31卷 / 04期

关键词：

CONDUCTING POLYMER; POLY(2,5-THIENYLENE VINYLENE); ELECTROCHEMICAL; N-TYPE DOPING; CYCLIC VOLTAMMOGRAM; OPTICAL ABSORPTION SPECTRUM; ELECTRON SPIN RESONANCE; POLARON; BIPOLARON; ELECTRONIC STATES;

D O I：

10.1143/JJAP.31.1107

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Evidence for electrochemical n-type doping of poly(2,5-thienylene vinylene) (PTV) is obtained from in situ measurements of a cyclic voltammogram, optical absorption spectrum and electron spin resonance. Bipolaron levels in the gap states appear upon n-type doping and the electronic band scheme of PTV is discussed.

引用

页码：1107 / 1111

页数：5

共 18 条

[1] PREPARATION AND ELECTRICAL-CONDUCTIVITY OF POLY(1,4-NAPHTHALENE VINYLENE) [J].

ANTOUN, S ;

GAGNON, DR ;

KARASZ, FE ;

LENZ, RW .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1986, 24 (10) :503-509

[2] ELECTROCHEMICAL POLYMERIZATION OF PYRROLE [J].

DIAZ, AF ;

KANAZAWA, KK ;

GARDINI, GP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (14) :635-636

[3] NEW ROUTES TO CONJUGATED POLYMERS .1. A 2 STEP ROUTE TO POLYACETYLENE [J].

EDWARDS, JH ;

FEAST, WJ ;

BOTT, DC .

POLYMER, 1984, 25 (03) :395-398

[4] ELECTRON-SPIN RESONANCE OF POLYACETYLENE AND ASF5-DOPED POLYACETYLENE [J].

GOLDBERG, IB ;

CROWE, HR ;

NEWMAN, PR ;

HEEGER, AJ ;

MACDIARMID, AG .

JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (03) :1132-1136

[5] HIGHLY-CONDUCTING, POLY(2,5-THIENYLENE VINYLENE) PREPARED VIA A SOLUBLE PRECURSOR POLYMER [J].

JEN, KY ;

MAXFIELD, M ;

SHACKLETTE, LW ;

ELSENBAUMER, RL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) :309-311

[6] FACILE PREPARATION OF HIGH-MOLECULAR-WEIGHT, HIGHLY CONDUCTIVE POLY(2,5-FURYLENE VINYLENE) [J].

JEN, KY ;

JOW, TR ;

ELSENBAUMER, RL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (14) :1113-1115

[7] CYCLE LIFE, STABILITY, AND CHARACTERISTICS OF COLOR SWITCHING CELLS UTILIZING POLYTHIOPHENE FILMS [J].

KANETO, K ;

AGAWA, H ;

YOSHINO, K .

JOURNAL OF APPLIED PHYSICS, 1987, 61 (03) :1197-1205

[8]

KANETO K, 1984, JPN J APPL PHYS, V23, P189

[9] HIGH MOLECULAR-WEIGHT POLYPHENYLENE VINYLENE [J].

KARASZ, FE ;

CAPISTRAN, JD ;

GAGNON, DR ;

LENZ, RW .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 118 (1-4) :327-332

[10]

MURASE I, 1987, POLYM COMMUN, V28, P229

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