TEMPORARY ANIONS OF THE FLUOROETHYLENES

被引：92

作者：

CHIU, NS ^{[1
]}

BURROW, PD ^{[1
]}

JORDAN, KD ^{[1
]}

机构：

[1] UNIV PITTSBURGH, DEPT CHEM, PITTSBURGH, PA 15260 USA

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80082-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron transmission spectroscopy is employed to measure the gas phase electron affinities of the fluoroethylenes. Fluorination is found to destabilize the π* anions with respect to that of ethylene. The role of bond length changes as well as inductive and resonance effects is examined. © 1979.

引用

页码：121 / 126

页数：6

共 27 条

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Rabalais J.W., 1977, PRINCIPLES ULTRAVIOL

[22] ELECTRON TRANSMISSION SPECTROSCOPY - RARE-GASES [J].