TEMPORARY ANIONS OF THE FLUOROETHYLENES

被引：92

作者：

CHIU, NS ^{[1
]}

BURROW, PD ^{[1
]}

JORDAN, KD ^{[1
]}

机构：

[1] UNIV PITTSBURGH, DEPT CHEM, PITTSBURGH, PA 15260 USA

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80082-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron transmission spectroscopy is employed to measure the gas phase electron affinities of the fluoroethylenes. Fluorination is found to destabilize the π* anions with respect to that of ethylene. The role of bond length changes as well as inductive and resonance effects is examined. © 1979.

引用

收藏

页码：121 / 126

页数：6

相关论文

共 27 条

[1] RESONANT SCATTERING OF ELECTRONS BY MOLECULES [J].

BARDSLEY, JN ;

MANDL, F .

REPORTS ON PROGRESS IN PHYSICS, 1968, 31 :471-&

[2] RELATIVE STABILITY OF 1,2-DIFLUOROETHYLENES [J].

BINKLEY, JS ;

POPLE, JA .

CHEMICAL PHYSICS LETTERS, 1977, 45 (02) :197-200

[3] OVERLAPPING SPHERES X-ALPHA CALCULATIONS OF THE ELECTRON-AFFINITIES AND IONIZATION-POTENTIALS OF ETHYLENE, PARABENZOQUINONE AND THEIR PERFLUORO DERIVATIVES [J].

BLOOR, JE ;

PAYSEN, RA ;

SHERROD, RE .

CHEMICAL PHYSICS LETTERS, 1979, 60 (03) :476-482

[4] Virtual negative ion spectra of hydrocarbons [J].

Boness, M. J. W. ;

Larkin, I. W. ;

Hasted, J. B. ;

Moore, L. .

CHEMICAL PHYSICS LETTERS, 1967, 1 (07) :292-294

[5] N(1AG), T(3B1U), AND V(1B1U) STATES OF VERTICAL ETHYLENE [J].

BROOKS, BR ;

SCHAEFER, HF .

JOURNAL OF CHEMICAL PHYSICS, 1978, 68 (11) :4839-4847

[6] PERFLUORO EFFECT IN PHOTOELECTRON SPECTROSCOPY .1. NON-AROMATIC MOLECULES [J].

BRUNDLE, CR ;

BASCH, H ;

ROBIN, MB ;

KEUBLER, NA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (05) :1451-&

[7] MRD-CI STUDY OF THE VERTICAL 1(PI, PI-STAR) V-N TRANSITION OF ETHYLENE USING AN AO-BASIS WITH OPTIMIZED RYDBERG ND-PI-SPECIES AND 2 SEPARATE CARBON-D POLARIZATION FUNCTIONS [J].

BUENKER, RJ ;

SHIH, SK ;

PEYERIMHOFF, SD .

CHEMICAL PHYSICS, 1979, 36 (01) :97-111

[8] ELECTRON AFFINITIES OF ETHYLENE AND 1,3-BUTADIENE [J].

BURROW, PD ;

JORDAN, KD .

CHEMICAL PHYSICS LETTERS, 1975, 36 (05) :594-598

[9] GAS-PHASE ELECTRON-DIFFRACTION STUDY OF 6 FLUOROETHYLENES [J].

CARLOS, JL ;

KARL, RR ;

BAUER, SH .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1974, 70 :177-187

[10] ELECTRON-IMPACT SPECTROSCOPY OF FLUOROETHYLENES [J].

COGGIOLA, MJ ;

FLICKER, WM ;

MOSHER, OA ;

KUPPERMANN, A .

JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (07) :2655-2667