COMPOUNDS OF HYPERCOORDINATED GOLD(I) .2. SYNTHESIS AND MOLECULAR-STRUCTURE OF 2,2'-BIS(TRIPHENYLPHOSPHINEGOLD)DIPHENYLMETHANE

被引：9
作者：
BAUKOVA, TV
DYADCHENKO, VP
OLEINIKOVA, NA
LEMENOVSKII, DA
KUZMINA, LG
机构：
[1] MOSCOW MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 117234,RUSSIA
[2] RUSSIAN ACAD SCI,NS KURNAKOV GEN & INORGAN CHEM INST,MOSCOW 117907,RUSSIA
来源：
RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 06期
关键词：
HYPERCOORDINATED GOLD(I); ORGANIC DERIVATIVES; AGOSTIC INTERACTIONS; SYNTHESIS; DIPHENYLMETHANE; X-RAY DIFFRACTION STUDY;
D O I：
10.1007/BF01558082
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A binuclear organic derivative of gold(I) with diphenylmethane CH2(C6H4)(2)(AuPPh(3))(2) has been prepared by the reaction of 2,2'-dilithiumdiphenylmethane with ClAuPPh(3). X-ray analysis of this compound revealed a transoid conformation of the molecule with agostic bonds between the gold atoms and methylene hydrogens. The complex was characterized by IR,H-1 and P-31 NMR, and mass spectral data.
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页码：1063 / 1068
页数：6
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