1-(2-Methoxyphenyl)-2-{[2-(2-methoxy-phenyl)hydrazinylidene](nitro)methyl}-diazene

被引：6

作者：

von Eschwege, Karel G. ^{[1
]}

Muller, Fabian ^{[1
]}

Hill, Tania N. ^{[1
]}

机构：

[1] Univ Free State, Dept Chem, POB 339, ZA-9300 Bloemfontein, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

基金：

新加坡国家研究基金会;

关键词：

data-to-parameter ratio = 15.4; mean σ(C-C) = 0.002 Å; R factor = 0.037; single-crystal X-ray study; T = 100 K; wR factor = 0.110;

D O I：

10.1107/S1600536812004175

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C 15H 15N 5O 4, a nitro-formazan derivative, the formazan unit is essentially planar with an r.m.s. deviation of 0.0204 (6) Å and adopts a closed syn,s-cis configuration with an intramolecular N - H⋯N hydrogen bond. The formazan plane makes dihedral angles of 4.32 (5) and 24.35 (5)° with the benzene rings. The dihedral angle between the formazan plane and the nitro group is 12.58 (8)°. In the crystal, C - H⋯O interactions connect the molecules into an inversion dimer.

引用

页码：O609 / U1457

页数：9

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