RUTHENIUM COMPLEX-CATALYZED NOVEL TRANSFORMATION OF ALKYL FORMATES

被引：20

作者：

KONDO, T

KAJIYA, S

TANTAYANON, S

WATANABE, Y

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,SAKYO KU,KYOTO 60601,JAPAN

[2] CHULALONGKORN UNIV,FAC SCI,DEPT CHEM,BANGKOK 10330,THAILAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 489卷 / 1-2期

关键词：

RUTHENIUM; CATALYSIS; ALKYL; ARENE; ALKENE; ALCOHOL;

D O I：

10.1016/0022-328X(94)05150-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The following ruthenium-catalyzed novel transformations of alkyl formates have been developed: (1) selective decarbonylation of alkyl formates to the corresponding alcohols; (2) alkylation of arenes and alkenes using alkyl formates as an alkylating reagent via decarboxylation. Also the ruthenium-catalyzed addition of alcohols to alkenes has been developed as an appendant reaction, providing an effective method for the protection of alcohols.

引用

页码：83 / 91

页数：9

共 54 条

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Ali B. E., 1992, J MOL CATAL, V77, P7

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