PYROLYSIS OF BENZENE-NAPHTHALENE MIXTURES - A TEMPERATURE-DEPENDENCE STUDY

被引:3
作者
DESTEFANIS, A [1 ]
PEREZ, G [1 ]
POSSAGNO, E [1 ]
LILLA, E [1 ]
机构
[1] CNR,IST CHIM NUCL,I-00016 MONTEROTONDO,ITALY
关键词
D O I
10.1016/0045-6535(94)90070-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The pyrolysis of benzene-naphthalene mixtures was carried out in the range of 450-570-degrees-C and the principal products were determined. The yields of all the products increase at higher temperatures. A measure of the rates of formation of biphenyl and 1,2'-binaphthyl, indicates the occurrence of a slight difference between their activation energies. The presence of alumina in the system has been also investigated.
引用
收藏
页码:1255 / 1259
页数:5
相关论文
共 12 条
[1]  
BADGER GM, 1965, PROGR PHYS ORG CHEM, V3, P1
[2]   HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC SEPARATION AND IDENTIFICATION OF PYROLYSIS PRODUCTS OF BENZENE [J].
BASSANELLI, R ;
PEREZ, G ;
POSSAGNO, E ;
POLCARO, C .
JOURNAL OF CHROMATOGRAPHY, 1983, 280 (01) :142-145
[3]   PYROLYSIS OF ETHYLBENZENE [J].
BROOKS, CT ;
PEACOCK, SJ ;
REUBEN, BG .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1982, 78 :3187-3202
[4]  
EICEMAN GA, 1981, ANAL CHEM, V48, P181
[5]   FORMATION OF ISOMERIC TERPHENYLS AND TRIPHENYLENE BY PYROLYSIS OF BENZENE [J].
JACOBELLI, C ;
PEREZ, G ;
POLCARO, C ;
POSSAGNO, E ;
BASSANELLI, R ;
LILLA, E .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1983, 5 (03) :237-243
[6]   A REVIEW OF ORGANIC EMISSIONS FROM SELECTED COMBUSTION PROCESSES [J].
JUNK, GA ;
FORD, CS .
CHEMOSPHERE, 1980, 9 (04) :187-230
[7]  
KIRK PS, 1974, ADV CHEM, V131, P237
[8]   LIQUEFACTION OF COAL IN HYDROGEN-DONOR AND NON-DONOR VEHICLES [J].
NEAVEL, RC .
FUEL, 1976, 55 (03) :237-242
[9]   PYROLYSIS OF BENZENE NAPHTHALENE MIXTURES [J].
PEREZ, G ;
CRISTALLI, A ;
LILLA, E .
CHEMOSPHERE, 1991, 22 (3-4) :279-284
[10]   ETHYLBENZENE PYROLYSIS - BENZYL C-C OR C-H BOND HOMOLYSIS [J].
ROBAUGH, DA ;
TSANG, W ;
FAHR, A ;
STEIN, SE .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1986, 90 (01) :77-84