REACTION OF LITHIUM SILYLAMIDES WITH CARBON-MONOXIDE LEADING TO CARBAMOYLSILANES

被引：30

作者：

ORITA, A ^{[1
]}

OHE, K ^{[1
]}

MURAI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 04期

关键词：

D O I：

10.1021/om00016a068

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Carbamoylsilanes, a hitherto little known class of compounds, are obtained by the reaction of lithium silylamides with carbon monoxide followed by quenching with methyl iodide. The reaction involves initial formation of a carbamoyllithium species and subsequent rearrangement of the silyl group to give a lithium (silylcarbonyl)amide.

引用

页码：1533 / 1536

页数：4

共 30 条

[21] SYNTHESIS AND CHEMISTRY OF ACYL SILANES [J].

PAGE, PCB ;

KLAIR, SS ;

ROSENTHAL, S .

CHEMICAL SOCIETY REVIEWS, 1990, 19 (02) :147-195

[22] CARBAMYLSILANES - A NEW CLASS OF ORGANOSILICON COMPOUND [J].

PEDDLE, GJD ;

WALSINGH.RW .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (09) :462-&

[23] CARBON CARBON BOND FORMATION THROUGH THE CARBONYLATION OF LITHIUM DIALKYLAMIDES - ONE-POT SYNTHESIS OF N-ALKYL-SUBSTITUTED FORMAMIDES, GLYOXYLAMIDES, AND HYDROXYMALONAMIDES [J].

PEREZ, DG ;

NUDELMAN, NS .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (02) :408-413

[24] CARBONYLATION OF LITHIUM MONOALKYLAMIDES TO GIVE N-LITHIO(ALKYL)FORMAMIDES [J].

RAUTENSTRAUCH, V ;

JOYEUX, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (01) :85-86

[25] CARBONYLATION OF LITHIUM DIALKYLAMIDES TO GIVE CARBAMOYLLITHIUMS [J].

RAUTENSTRAUCH, V ;

JOYEUX, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (01) :83-85

[26]

RICCI A, 1989, SYNTHESIS-STUTTGART, P647

[27]

SANDLER SR, 1983, ORGANIC FUNCTIONAL G, V1, P323

[28] FLUORIDE-CATALYZED CONVERSION OF ACYLSILANES TO ALDEHYDES AND KETONES [J].

SCHINZER, D ;

HEATHCOCK, CH .

TETRAHEDRON LETTERS, 1981, 22 (20) :1881-1884

[29] SYNTHESIS OF ALPHA-AMINOCYCLOBUTANONES BY THE PHOTOLYTIC REACTION OF CHROMIUM AMINOCARBENE COMPLEXES WITH OLEFINS [J].

SODERBERG, BC ;

HEGEDUS, LS .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (06) :2209-2212

[30] CARBOXYSILANES AND CARBOXYGERMANES .3. IONIZATION CONSTANTS OF TRIORGANOSILANE- AND TRIORGANOGERMANECARBOXYLIC ACIDS IN ETHANOL-WATER AND DIMETHYL SULFOXIDE MEDIA [J].

STEWARD, OW ;

DZIEDZIC, JE ;

JOHNSON, JS ;

FROHLIGE.JO .

JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (23) :3480-&

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