Electroconductivity of anion-radical TCNQ salts containing cations [M(bipy)(3)](2+) (M - Fe, Ni or Zn)

被引：2
|
作者：
Vasylets, G. Y. [1 ]
Khotkevich, A., V [1 ,2 ]
Bukrinev, A. S. [1 ]
Krasnyi, A. S. [1 ]
Starodub, V. A. [3 ]
Kravchenko, A. A. [1 ]
Medviedie, V. V. [4 ]
机构：
[1] V Karazin Kharkiv Natl Univ, Appl Chem Dept, 4 Svobody Sq, UA-61022 Kharkov, Ukraine
[2] Natl Acad Sci Ukraine, B Verkin Inst Low Temp Phys & Engn, UA-61103 Kharkov, Ukraine
[3] Jan Kochanowski Univ Humanities & Sci, Inst Chem, PL-25406 Kielce, Poland
[4] Natl Acad Sci Ukraine, STC Inst Single Crystals, UA-61178 Kharkov, Ukraine
来源：
FUNCTIONAL MATERIALS | 2015年 / 22卷 / 03期
关键词：
tetracyanoquinodimethane; electrical resistance; semiconductor; Peierls transition;
D O I：
10.15407/fm22.03.338
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Electrical resistance temperature dependence of three TCNQ anion-radical salts of complex composition containing cations [M-II(bipy)(3)](2+) (M - Fe, Ni or Zn, bipy - 2,2'-dipyridil) have been studied. Measurements have been performed in the range 180-300 K on tableted samples. The compound exhibit semiconducting properties and undergo the Peierls transition. Specific resistance at room temperature is of 7.7 Omega.cm for Fe containing salt and 2.3.10(-2) Omega.cm and 2.5.10(-2) Omega.cm for salts containing Ni and Zn, respectively.
引用
收藏
页码：338 / 341
页数：4
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