CHEMISTRY OF SINGLET OXYGEN - DYE-SENSITIZED PHOTOOXYGENATION OF ARYLALLENES

被引：9

作者：

ERDEN, I

MARTINEZ, TR

机构：

[1] Department of Chemistry and Biochemistry, San Francisco State University, San Francisco

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 16期

关键词：

D O I：

10.1016/S0040-4039(00)85981-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-Arylallenes react with singlet oxygen via 1,2-and 1,4-cycloaddition modes giving rise to three types of carbonyl fragments. 1,1-Diphenyl- and 1-methyl-1-phenylallenes react predominantly by the 1,4-mode. Plausible mechanisms are discussed for the formation of the observed products.

引用

页码：1859 / 1862

页数：4

共 22 条

[1]

Bloodworth A.J., 1985, SINGLET OXYGEN 1, P93

[2]

BRUICE PY, 1973, J AM CHEM SOC, V95, P6041

[3] CHEMISTRY OF ALLENE OXIDES .5. [J].