Far infrared spectra of several Fe(III) complexes with spin S=3/2

被引：21

作者：

Brackett, G. C. ^{[1
,2
]}

Richards, P. L. ^{[1
,2
]}

Wickman, H. H. ^{[3
]}

机构：

[1] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA

[2] Lawrence Radiat Lab, Inorgan Mat Res Div, Berkeley, CA 94720 USA

[3] Bell Telephone Labs, Murray Hill, NJ 07974 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 02期

关键词：

D O I：

10.1016/0009-2614(70)80135-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The far infrared transmission spectra of seven bis (N, N dialkyl dithiocarbamato) Fe(III) halides have been measured at 4.2 degrees K in applied magnetic fields up to 52 kOe. The paramagnetic spectra are closely consistent with the spin hamiltonian H = g mu H-B.S + D[S-z(2)-S(S+1)/3] + E[S-x(2)-S-y(2)] for S=3/2, E/D < 1. and values of D between -2.35 and + 8.15 cm(-1). The zero field ferromagnetic resonance of [(C2H5)(2)NCS2](2) FeCl in the ordered state Gas observed at 3.85 cm(-1).

引用

页码：75 / 78

页数：4

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