COMPUTER EVALUATION OF ENTROPY TITRATION DATA . CALORIMETRIC DETERMINATION OF LOG BETAI DELTAHI DEGREES AND DELTASI DEGREES VALUES FOR SILVE(I)- AND COPPER(2)-PYRIDINE SYSTEMS

被引：72
作者：
IZATT, RM
EATOUGH, D
SNOW, RL
CHRISTEN.JJ
机构：
[1] Departments of Chemistry and Chemical Engineering, Brigham Young University, Provo
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1968年 / 72卷 / 04期
关键词：
D O I：
10.1021/j100850a023
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Log βi, ΔHi°, and ΔSi° values have been determined in aqueous solution at 25° using a calorimetric titration procedure for the stepwise formation of AgPy2+ and CuPy42+ (Py = pyridine) from their constituent ions. The results agree well with previously determined values where available and demonstrate that titration calorimetry can be used to determine log K, ΔH°, and ΔS° values for metal-ligand systems involving simultaneous equilibria. Four iterative methods of data analysis are compared and discussed.
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页码：1208 / &
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