BAEYER-VILLIGER MONOOXYGENASE-DEPENDENT BIOTRANSFORMATIONS - STEREOSPECIFIC HETEROATOM OXIDATIONS BY CAMPHOR-GROWN PSEUDOMONAS-PUTIDA TO PRODUCE CHIRAL SULFOXIDES

被引：19

作者：

BEECHER, J ^{[1
]}

RICHARDSON, P ^{[1
]}

WILLETTS, A ^{[1
]}

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4QG,DEVON,ENGLAND

来源：

BIOTECHNOLOGY LETTERS | 1994年 / 16卷 / 09期

关键词：

D O I：

10.1007/BF00128623

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Camphor-grown Pseudomonas putida NCIMB 10007 catalysed the stereospecific oxygenation of various alkyl aryl sulfides to equivalent S-(-)-sulfoxides. The structure of the sulfide significantly influenced both the yield and the optical. purity of the predominant product. The biotransformations were catalysed exclusively by the. Baeyer-Villiger monooxygenases present in camphor-grown P. putida.

引用

页码：909 / 912

页数：4

共 14 条

[1] EFFECTS OF SUBSTRATE STRUCTURE ON THE ENANTIOSELECTIVITY AND STEREOCHEMICAL COURSE OF SULFOXIDATION CATALYZED BY CYCLOHEXANONE MONOOXYGENASE
CARREA, G
REDIGOLO, B
RIVA, S
COLONNA, S
GAGGERO, N
BATTISTEL, E
BIANCHI, D
[J]. TETRAHEDRON-ASYMMETRY, 1992, 3 (08) : 1063 - 1068
[2] CONRAD HE, 1965, J BIOL CHEM, V240, P495
[3] BIOTRANSFORMATIONS BY MICROBIAL BAEYER-VILLIGER MONOOXYGENASES STEREOSELECTIVE LACTONE FORMATION INVITRO BY COUPLED ENZYME-SYSTEMS
GROGAN, G
ROBERTS, S
WILLETTS, A
[J]. BIOTECHNOLOGY LETTERS, 1992, 14 (12) : 1125 - 1130
[4] CAMPHOR-GROWN PSEUDOMONAS-PUTIDA, A MULTIFUNCTIONAL BIOCATALYST FOR UNDERTAKING BAEYER-VILLIGER MONOOXYGENASE-DEPENDENT BIOTRANSFORMATIONS
GROGAN, G
ROBERTS, S
WAN, P
WILLETTS, A
[J]. BIOTECHNOLOGY LETTERS, 1993, 15 (09) : 913 - 918
[5] SOME BAEYER-VILLIGER OXIDATIONS USING A MONOOXYGENASE ENZYME FROM PSEUDOMONAS-PUTIDA NCIMB-10007
GROGAN, G
ROBERTS, SM
WILLETTS, AJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) : 699 - 701
[6] Gunsalus I.C., 1971, CRC CR REV MICROBIOL, V1, P291, DOI [10.3109/10408417109104484, DOI 10.3109/10408417109104484]
[7] CHIRAL SULFOXIDATION BY BIOTRANSFORMATION OF ORGANIC SULFIDES
HOLLAND, HL
[J]. CHEMICAL REVIEWS, 1988, 88 (03) : 473 - 485
[8] STUDIES ON THE CHIRALITY OF SULFOXIDATION CATALYZED BY BACTERIAL FLAVOENZYME CYCLOHEXANONE MONO-OXYGENASE AND HOG LIVER FLAVIN ADENINE-DINUCLEOTIDE CONTAINING MONO-OXYGENASE
LIGHT, DR
WAXMAN, DJ
WALSH, C
[J]. BIOCHEMISTRY, 1982, 21 (10) : 2490 - 2498
[9] RETTIE AE, 1990, MOL PHARMACOL, V37, P643
[10] Sokatch JR, 1986, BACTERIA, V10, P557

← 1 2 →