BAEYER-VILLIGER MONOOXYGENASE-DEPENDENT BIOTRANSFORMATIONS - STEREOSPECIFIC HETEROATOM OXIDATIONS BY CAMPHOR-GROWN PSEUDOMONAS-PUTIDA TO PRODUCE CHIRAL SULFOXIDES

被引：19

作者：

BEECHER, J ^{[1
]}

RICHARDSON, P ^{[1
]}

WILLETTS, A ^{[1
]}

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4QG,DEVON,ENGLAND

来源：

BIOTECHNOLOGY LETTERS | 1994年 / 16卷 / 09期

关键词：

D O I：

10.1007/BF00128623

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Camphor-grown Pseudomonas putida NCIMB 10007 catalysed the stereospecific oxygenation of various alkyl aryl sulfides to equivalent S-(-)-sulfoxides. The structure of the sulfide significantly influenced both the yield and the optical. purity of the predominant product. The biotransformations were catalysed exclusively by the. Baeyer-Villiger monooxygenases present in camphor-grown P. putida.

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页码：909 / 912

页数：4

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