Dimethylbis(2-methylquinolin-8-olato kappa(2) N,O)tin(IV)

被引：0
|
作者：
Najafi, Ezzatollah [1 ]
Amini, Mostafa M. [1 ]
Ng, Seik Weng [2 ,3 ]
机构：
[1] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran
[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[3] King Abdulaziz Univ, Fac Sci, Chem Dept, Jeddah 80203, Saudi Arabia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 18.7; mean ω(C-C) = 0.010 Å; R factor = 0.039; single-crystal X-ray study; T = 295 K; wR factor = 0.094;
D O I：
10.1107/S1600536812047393
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Sn IV cation in the title compound, [Sn(CH3)(2)(C10H8NO)(2)], is N, O-chelated by two 2-methylquinolin-8olate anions and coordinated by two methyl groups in a skewtrapezoidal bipyramidal geometry. In the molecule, the two quinoline ring systems are twisted to one another at 10.91 (18)degrees. The dimethyltin skeleton [C-Sn-C = 149.6 (2)degrees] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak intermolecular C-H center dot center dot center dot O hydrogen bonding occurs in the crystal.
引用
收藏
页码：M1551 / +
页数：8
相关论文
共 50 条
  • [31] (Nitrato-kappa O-2,O')bis(1,1'-phenanthroline-kappa(2) N, N') copper(II) tricyanomethanide
    Lackova, Katarina
    Potocnak, Ivan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1553 - +
  • [32] Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato- kappa(2) O,O ')bis(ethanol-kappa O)-cobalt(II)
    Idemudia, Omoruyi G.
    Hosten, Eric C.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1107 - +
  • [33] (Dimethyl sulfoxide-kappa O)[2-({(ethylsul-fanyl)[2-(2-oxidobenzylidene-kappa O) hydrazinylidene-kappa N-2]methyl}iminomethyl)-phenolato-kappa O] dioxidouranium(VI)
    Takjoo, Reza
    Ng, Seik Weng
    Tiekink, Edward R. T. }
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M244 - U377
  • [34] catena-Poly[[tetra-mu-benzoato-kappa O-8:O '-dicopper(II)]-mu-[N-(pyridin-4-yl)nicotinamide]-kappa N-2:N '-[dibenzoato-kappa O-2-copper(II)]-mu-[N-(pyridin-4-yl) nicotinamide]-kappa N-2:N ']
    Kraft, Peter E.
    LaDuca, Robert L.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1049 - +
  • [35] Bis(acetato-kappa O-2,O ')(4,4 '-dimethyl-2,2 '-bipyridine-kappa N-2,N ')zinc
    Harvey, Miguel A.
    Suarez, Sebastian A.
    Ibanez, Andres
    Doctorovich, Fabio
    Baggio, Ricardo
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1377 - +
  • [36] Bis{mu-2-[(pyrimidin-2-yl) aminomethyl]phenolato}-kappa N-2(1):O;kappa O-2:N-1-bis({2[( pyrimidin-2-yl-kappa N) aminomethyl] phenol} silver(I)) dihydrate
    Gao, Shan
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1538 - +
  • [37] Tris(2,2'-bipyridine-kappa N-2,N') cobalt(III) tris(oxalato-kappa O-2(1),O-2) ferrate(III) monohydrate
    Chygorin, Eduard N.
    Petrusenko, Svitlana R.
    Kokozay, Volodymyr N.
    Omelchenko, Irina V.
    Shishkin, Oleg V.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M233 - U314
  • [38] (2,2 '-Bipyridine-kappa N-2,N ')tetrakis(dimethyl sulfoxide-kappa O)copper(II) bis(perchlorate)
    Iskenderov, Turganbay
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M448 - +
  • [39] (2,2 '-Bipyridine-kappa N-2,N') bis(4-formylbenzoato-kappa O-1) copper(II)
    Qi, Jin-Li
    Xu, Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1062 - +
  • [40] Trichlorido(6-methyl-2,2 '-bipyridinej kappa N-2,N ')(dimethylsulfoxide-kappa O)indium(III)
    Shirvan, Sadif A.
    Dezfuli, Sara Haydari
    Golabi, Elyas
    Gholamzadeh, Mohammad Amin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1327 - +
12345