Dimethylbis(2-methylquinolin-8-olato kappa(2) N,O)tin(IV)

被引：0
|
作者：
Najafi, Ezzatollah [1 ]
Amini, Mostafa M. [1 ]
Ng, Seik Weng [2 ,3 ]
机构：
[1] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran
[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[3] King Abdulaziz Univ, Fac Sci, Chem Dept, Jeddah 80203, Saudi Arabia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 18.7; mean ω(C-C) = 0.010 Å; R factor = 0.039; single-crystal X-ray study; T = 295 K; wR factor = 0.094;
D O I：
10.1107/S1600536812047393
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Sn IV cation in the title compound, [Sn(CH3)(2)(C10H8NO)(2)], is N, O-chelated by two 2-methylquinolin-8olate anions and coordinated by two methyl groups in a skewtrapezoidal bipyramidal geometry. In the molecule, the two quinoline ring systems are twisted to one another at 10.91 (18)degrees. The dimethyltin skeleton [C-Sn-C = 149.6 (2)degrees] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak intermolecular C-H center dot center dot center dot O hydrogen bonding occurs in the crystal.
引用
收藏
页码：M1551 / +
页数：8
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