INCLUSION COMPLEXATION OF SODIUM ALKYL SULFATES WITH BETA-CYCLODEXTRIN - H-1-NMR STUDY

被引：40

作者：

GUO, QX

LI, ZZ

REN, T

ZHU, XQ

LIU, YC

机构：

[1] LANZHOU UNIV,NATL LAB APPL ORGAN CHEM,LANZHOU 730000,PEOPLES R CHINA

[2] LANZHOU UNIV,DEPT CHEM,LANZHOU 73000,PEOPLES R CHINA

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1994年 / 17卷 / 02期

关键词：

ASSOCIATION CONSTANT; BETA-CYCLODEXTRIN; INCLUSION; NMR; SURFACTANT;

D O I：

10.1007/BF00711855

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The association of anionic surfactants, viz., sodium alkyl sulfates, CnH2n+1OSO3Na (n = 5, 6, 7, 8, 9, 10, 12), with beta-cyclodextrin has been investigated by means of NMR spectroscopy. The measurements of chemical shift changes of certain protons of both host and guest molecules indicated 1 : 1 inclusion complex formation. The association constants (K(a)) and standard free energy changes (-DELTAG0) for the inclusion complexation reaction vary as a function of the hydrocarbon chain length of the surfactants.

引用

页码：149 / 156

页数：8

共 15 条

[1] A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].

BENESI, HA ;

HILDEBRAND, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707

[2] DISPOSITION REQUIREMENTS FOR BINDING IN AQUEOUS-SOLUTION OF POLAR SUBSTRATES IN CYCLOHEXAAMYLOSE CAVITY [J].

BERGERON, RJ ;

CHANNING, MA ;

GIBEILY, GJ ;

PILLOR, DM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) :5146-5151

[3] AN ELECTROCHEMICAL STUDY OF MIXED-SOLUTIONS OF BETA-CYCLODEXTRIN AND SODIUM DODECYL-SULFATE [J].

GEORGES, J ;

DESMETTRE, S .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1987, 118 (01) :192-200

[4]

JERCHEL D, 1956, Z NATURFORSCH PT B, V11, P681

[5]

JUNGUERA E, 1992, J PHYS CHEM-US, V96, P4533

[6] EFFECT OF THE PRESENCE OF BETA-CYCLODEXTRIN ON THE MICELLIZATION PROCESS OF SODIUM DODECYL-SULFATE OR SODIUM PERFLUOROOCTANOATE IN WATER [J].

JUNQUERA, E ;

TARDAJOS, G ;

AICART, E .

LANGMUIR, 1993, 9 (05) :1213-1219

[7] CAN TMS AND DSS BE USED AS NMR REFERENCES FOR CYCLODEXTRIN SPECIES IN AQUEOUS-SOLUTION [J].

LI, ZZ ;

GUO, QX ;

REN, T ;

ZHU, XQ ;

LIU, YC .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1993, 15 (01) :37-42

[8] CONDUCTOMETRIC STUDIES ON ASSOCIATION OF CYCLODEXTRIN WITH COLLOIDAL ELECTROLYTES [J].

OKUBO, T ;

KITANO, H ;

ISE, N .

JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (24) :2661-2664

[9] SURFACTANT CYCLODEXTRIN INTERACTIONS BY CONDUCTANCE MEASUREMENTS [J].

PALEPU, R ;

REINSBOROUGH, VC .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1988, 66 (02) :325-328

[10] ASSOCIATION OF ANIONIC SURFACTANTS WITH BETA-CYCLODEXTRIN - FLUORESCENCE-PROBED STUDIES ON THE 1-1 AND 1-2 COMPLEXATION [J].

PARK, JW ;

SONG, HJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (17) :6454-6458

← 1 2 →