MIXED DIMETHYLSULFOXIDE-THIOCARBONYL DONOR COMPLEXES OF PLATINUM(II) HALIDES

被引：1

作者：

FARAGLIA, G ^{[1
]}

BARBARO, F ^{[1
]}

SITRAN, S ^{[1
]}

机构：

[1] CNR,IST CHIM & TECNOL RADIOELEMENTI,I-35020 PADUA,ITALY

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1990年 / 21卷 / 01期

关键词：

complexes; dmso; Platinum(II) thioamides; properties;

D O I：

10.1080/00958979009408184

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The platinum(II) halide adducts cis-[Pt(DMSO)(L)X2], where L = 2,6-dimethyl-4H-pyran-4-thione (DMTP), N, N’-dimethylthioacetamide (DMTA) or N, N-dimethylthioformamide (DMTF) and X = Cl or Br have been prepared and characterized by elemental analysis, by infrared and nmr (1H and 13C) spectroscopy and by thermogravimetric measurements (TG, DTG and DTA). When dissolved in dimethylsulfoxide, the DMTA complexes tend to slowly release the thioamide molecule, whereas the DMTP and DMTF adducts are stable for several weeks, as suggested by the permanence of 195Pt coupling satellites in selected nmr signals. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：63 / 70

页数：8

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