EPR of Ag° site conversion in gamma-irradiated frozen AgNo3 ices

被引:18
作者
Bales, B. L. [1 ]
Kevan, L.
机构
[1] Univ Kansas, Dept Phys, Lawrence, KS 66044 USA
[2] Univ Kansas, Dept Chem, Lawrence, KS 66044 USA
基金
美国国家航空航天局;
关键词
D O I
10.1016/0009-2614(69)85040-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Gamma ratiolysis of AgNO3 ice at 77 degrees K forms Ag degrees in 4 magnetically distinct sites due to different orientations of water dipoles. Site interconversion which occurs by rotation of water dipoles due to removal of the electric field of Ag+ is studied by EPR.
引用
收藏
页码:484 / 487
页数:4
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