DETECTION OF NITROGEN-ATOMS PRODUCED BY PREDISSOCIATION OF SUPEREXCITED RYDBERG STATES OF NO

被引：32

作者：

FUJII, A

MORITA, N

机构：

[1] Institute for Molecular Science, Okazaki, 444, Myodaiji

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 182卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(91)80219-N

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Predissociation processes of superexcited Rydberg states (v = 1, n = 8 - 17, l = s, p and f) of the NO molecule have been investigated by detecting the fragment nitrogen atom with a resonance-enhanced multiphoton ionization (REMPI) technique. As a result, the N (2D) production predicted by theoretical calculations has been confirmed. Moreover, the unexpected generation of N (4S) has also been observed. Yields of the fragment atoms are strongly dependent on both the principal and angular momentum quantum numbers of the Rydberg electron.

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页码：304 / 309

页数：6

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