ENANTIOSELECTIVE EPOXIDATION OF STYRENE DERIVATIVES BY CHLOROPEROXIDASE CATALYSIS

被引：66

作者：

COLONNA, S

GAGGERO, N

CASELLA, L

CARREA, G

PASTA, P

机构：

[1] CNR,IST CHIM ORMONI,I-20133 MILAN,ITALY

[2] UNIV PAVIA,DIPARTIMENTO CHIM GEN,I-27100 PAVIA,ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(00)80243-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chloroperoxidase catalysed epoxidation of styrene derivatives by t-BuOOH preferentially gives (R) oxides with ee values between 28 and 68%. The data support the view of oxygen delivery from the ferryl oxygen directly to the substrate.

引用

页码：1325 / 1330

页数：6

共 13 条

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