Crystal structure of S-hexyl (E)-3-(4-methoxybenzylidene)dithiocarbazate

被引:6
作者
Begum, M. S. [1 ]
Howlader, M. B. H. [1 ]
Miyatake, R. [2 ]
Zangrando, E. [3 ]
Sheikh, M. C. [4 ]
机构
[1] Rajshahi Univ, Dept Chem, Rajshahi 6205, Bangladesh
[2] Toyama Univ, Ctr Environm Conservat & Res Safety, Toyama 9308555, Japan
[3] Dept Chem & Pharmaceut Sci, I-34127 Trieste, Italy
[4] Toyama Univ, Fac Engn, Dept Appl Chem, Toyama 9308555, Japan
关键词
crystal structure; dithiocarbazate; S-containing Schiff bases; hydrogen bonding;
D O I
10.1107/S2056989015003199
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C15H22N2OS2, the dithiocarbazate group adopts an EE conformation with respect to the C=N bond of the benzylidene moiety. The hexyl side chain adopts an extended conformation and the C-S-C-C torsion angle is -93.36 (13)degrees. In the crystal, inversion dimers linked by pairs of N-H center dot center dot center dot S hydrogen bonds generate R-2(2)(8) loops.
引用
收藏
页码:O199 / +
页数:8
相关论文
共 5 条
[1]   SIR92 - a program for automatic solution of crystal structures by direct methods [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, G ;
GUAGLIARDI, A ;
BURLA, MC ;
POLIDORI, G ;
CAMALLI, M .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435
[2]   Crystal structure of S-hexyl (E)-3-(4-methylbenzylidene)dithiocarbazate [J].
Howlader, M. B. H. ;
Begum, M. S. ;
Sheikh, M. C. ;
Miyatake, R. ;
Zangrando, E. .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 :O103-U440
[3]  
Rigaku, 2010, CRYSTALSTRUCTURE
[4]  
Rigaku Corporation, 1995, ABSCOR
[5]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122