HYDRIDE-PROMOTED DEMETHYLATION OF METHYL PHENYL ETHERS

被引：35
|
作者：
MAJETICH, G
ZHANG, Y
WHELESS, K
机构：
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 47期
关键词：
D O I：
10.1016/S0040-4039(00)78482-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Solutions of L-Selectride or SuperHydride in refluxing THF efficiently deprotect methyl phenyl ethers. L-Selectride is the more effective reagent, while electron-poor arenes work best. Unlike other hydride sources, these reagents permit ether cleavage without the reduction of aryl halides.
引用
收藏
页码：8727 / 8730
页数：4
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