INTRAMOLECULAR HEMOLYTIC SHIFTS .19. STEREOCHEMISTRY OF INDUCED DECOMPOSITION OF UNSATURATED PEROXIDES LEADING TO THE FORMATION OF 3-MEMBERED AND 4-MEMBERED HETEROCYCLES

被引：8

作者：

LUBEIGT, X

FLIES, F

BOURGEOIS, MJ

MONTAUDON, E

MAILLARD, B

机构：

[1] UNIV BORDEAUX 1,CHIM APPL LAB,F-33405 TALENCE,FRANCE

[2] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,CNRS,URA 35,F-33405 TALENCE,FRANCE

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1991年 / 69卷 / 08期

关键词：

UNSATURATED PEROXIDES; HOMOLYTIC INTRAMOLECULAR SUBSTITUTIONS; RADICAL ADDITIONS; OXYGENATED HETEROCYCLES;

D O I：

10.1139/v91-196

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Homolytic decomposition induced by addition of dichloromethyl radicals to beta- and gamma-unsaturated peroxides having a substituent on the chain linking the unsaturation and the peroxide function was studied. The stereochemistry of the heterocycles produced was determined by C-13 NMR and the stereoselectivity of intramolecular homolytic substitution on the peroxidic bond discussed.

引用

页码：1320 / 1325

页数：6