ARGON-ION LASER EXCITATION OF THE FLUOROSULFATE RADICAL

被引：9
|
作者：
WARREN, CH
机构：
[1] Department of Chemistry, Dalhousie University, Halifax, NS B3H 4J3, Canada
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 1980年 / 83卷 / 02期
关键词：
741.1; Light/Optics; -; 744.1; Lasers; General - 744.9 Laser Applications - 801.4 Physical Chemistry - 931.3 Atomic and Molecular Physics - 931.4 Quantum Theory; Quantum Mechanics;
D O I：
10.1016/0022-2852(80)90069-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Discrete visible fluorescence has been observed from excitation of the fluorosulfate radical with argon-ion laser excitation which falls within its visible electronic absorption spectrum. Ground-state fundamentals of the radical have been determined which are in agreement with those determined from the analysis of the hot bands in the electronic absorption spectrum. The analysis of the fluorescence spectrum is consistent with the molecule possessing C 3r symmetry in the ground electronic state. Copyright © 1980 by Academic Press, Inc.
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页码：451 / 461
页数：11
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