HIGHLY STEREOSELECTIVE SYNTHESIS OF (Z)-DOUBLE-BONDS OR (E)-DOUBLE-BONDS WITH CONFORMATIONAL CONTROL IN [3,3]SIGMATROPIC RING EXPANSION OF 8-MEMBERED THIONOCARBONATES

被引：13

作者：

HARUSAWA, S ^{[1
]}

OSAKI, H ^{[1
]}

FUJII, H ^{[1
]}

YONEDA, R ^{[1
]}

KURIHARA, T ^{[1
]}

机构：

[1] OSAKA UNIV PHARMACEUT SCI,2-10-65 KAWAI,MATSUBARA,OSAKA 580,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 38期

关键词：

D O I：

10.1016/S0040-4039(00)97875-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The highly stereoselective synthesis of (Z)- or (E)-double bonds in 1O-membered thiolcarbonates was successfully conducted by controling the chairlike-boatlike transition states in the [3,3]sigmatropic rearrangement of 8-membered thionocarbonates. © 1990.

引用

页码：5471 / 5474

页数：4

共 6 条

[1] THE HETERO-COPE REARRANGEMENT IN ORGANIC-SYNTHESIS [J].