THE INTRODUCTION OF SCF3 INTO AROMATIC SUBSTRATES USING CUSCF3 AND ALUMINA-SUPPORTED CUSCF3

被引：71
作者：
CLARK, JH
JONES, CW
KYBETT, AP
MCCLINTON, MA
MILLER, JM
BISHOP, D
BLADE, RJ
机构：
[1] BROCK UNIV,DEPT CHEM,ST CATHARINES L2S 3A1,ONTARIO,CANADA
[2] BDH LTD,POOLE BH12 4NN,DORSET,ENGLAND
[3] WELLCOME FDN LTD,BERKHAMSTED HP4 2DY,ENGLAND
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 48卷 / 02期
基金：
英国惠康基金;
关键词：
D O I：
10.1016/S0022-1139(00)80437-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Trifluoromethylthiocopper(I) has been readily prepared from the silver analogue, using a metathetical reaction with copper(I) bromide. Homogeneous CuSCF3 and the supported reagent CuSCF3-alumina have been compared in their reactivity towards aryl iodides, in order to form trifluoromethylaryl sulphides in good yields. © 1990.
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页码：249 / 255
页数：7
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