NEUTRON-DIFFRACTION STUDY OF CEMN2GE2, PRMN2GE2 AND NDMN2GE2 - EVIDENCE OF DOMINANT ANTIFERROMAGNETIC COMPONENTS WITHIN THE (001) MN PLANES IN FERROMAGNETIC THCR2SI2-TYPE MANGANESE TERNARY COMPOUNDS

被引:164
|
作者
WELTER, R
VENTURINI, G
RESSOUCHE, E
MALAMAN, B
机构
[1] UNIV NANCY 1,CHIM SOLIDE MINERAL LAB,CNRS,URA 158,F-54506 VANDOEUVRE NANCY,FRANCE
[2] CEA,DEPT RECH FONDAMENTALE MAT CONDENSEE,SPSMS,MDN,F-38054 GRENOBLE 9,FRANCE
关键词
NEUTRON DIFFRACTION; ANTIFERROMAGNETISM; FERROMAGNETISM; MANGANESE TERNARY COMPOUNDS;
D O I
10.1016/0925-8388(94)01378-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The magnetic properties of ThCr2Si2-type structure RMn(2)Ge(2) (R=Ce, Pr, Nd) compounds have been reinvestigated by the use of neutron diffraction experiments. The ferromagnetic ordering previously proposed to take place on the manganese sublattice is revised. The three compounds are characterized by mixed (001) Mn planes where ferro- and antiferromagnetic components coexist. In the temperature range 2-300 K, CeMn2Ge2 (T-c=320 K) exhibits an easy axis conical magnetic structure (cone semiangle (alpha approximate to 60 degrees) with a total Mn moment value of about 2.7 mu(B), at 2 K. Ce moments do not order above 1.6 K. At room temperature, PrMn2Ge2 (T-c=330 K) and NdMn2Ge2 (T-c=330 K) compounds exhibit an easy axis canted ferromagnetic structure (phi approximate to 60 degrees) while, at lower temperature (T<250 K), a conical magnetic structure takes place on the Mn sublattice (alpha approximate to 60 degrees). The rare earth sublattices orders ferromagnetically below about 100 K. In PrMn2Ge2, an easy axis prevails in the whole temperature range. At 2 K, the total Mn moment is about 2.8 mu(B), and the Pr moment value is about 29 mu(B). On the contrary, in NdMn,Ge, the easy axis rotates to the (001) plane below 250 K. At 2 K, the total Mn moment is about 2.7 mu(B), and the Nd moment value is about 2.3 mu(B). In all cases, the thermal dependence of the AF component suggests that an ordering temperature T-N not detected by magnetic moments, occurs at a temperature much higher than the Curie point. The results are compared with those of the related RMnSi, RMnGe and RMnSi(2) compounds. The evolution of the magnetic behaviour within the ThCr2Si2-type structure RMn(2)X(2) (X=Si, Ge) compounds is discussed.
引用
收藏
页码:204 / 215
页数:12
相关论文
共 33 条
  • [31] Crystal structure and magnetic properties of novel Hf3Ni2Si3-type R3Co2Ge3 compounds (R=Y, Sm, Tb-Tm)
    Morozkin, A. V.
    Nirmala, R.
    Yao, Jinlei
    Mozharivskyj, Y.
    Isnard, O.
    JOURNAL OF SOLID STATE CHEMISTRY, 2012, 196 : 93 - 99
  • [32] Magnetic States and Electronic Properties of Manganese-Based Intermetallic Compounds Mn2YAl and Mn3Z (Y = V, Cr, Fe, Co, Ni; Z = Al, Ge, Sn, Si, Pt)
    Marchenkov, Vyacheslav V.
    Irkhin, Valentin Yu.
    MATERIALS, 2023, 16 (19)
  • [33] Magnetization distribution in Cu0.6Mn2.4Ge2 ferromagnet from polarized and non-polarized neutron powder diffraction aided by density-functional theory calculations
    Tener, Zachary P.
    Yannello, Vincent
    Willis, Jenifer
    Garlea, V. Ovidiu
    Shatruk, Michael
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2021, 529