ISOLATION AND X-RAY STRUCTURE OF TRANS-3,5-BIS(2,4,6-TRI-TERT-BUTYLPHENYL)-1,2,3,5-DITHIADIPHOSPHOLANE 3,5-DISULFIDE

被引：7

作者：

TOYOTA, K

ISHIKAWA, Y

YOSHIFUJI, M

OKADA, K

HOSOMI, K

HIROTSU, K

机构：

[1] TOHOKU UNIV, FAC SCI, DEPT CHEM, SENDAI 980, JAPAN

[2] OSAKA CITY UNIV, FAC SCI, DEPT CHEM, OSAKA 558, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 12期

关键词：

D O I：

10.1246/cl.1991.2213

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A phosphorus-containing novel heterocyclic compound, trans-3,5-bis(2,4,6-tri-t-butylphenyl)-1,2,3,5-dithiadiphospholane 3,5-disulfide (trans-1), was isolated in the reaction of 1,3-bis(2,4,6-tri-t-butylphenyl)-1,3-diphosphaallene with sulfur and the structure of trans-1 was confirmed by the X-ray crystallography. Desulfurization of trans-1 afforded the corresponding trans-1,2,4-thiadiphosphetane 2,4-disulfide.

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页码：2213 / 2216

页数：4

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