REDUCTION OF ALIPHATIC NITRO-COMPOUNDS .3. EFFECT OF CIS-TRANS ISOMERIZATION ON THE ELECTROREDUCTION OF ALPHA-NITROCINNAMIC ACID-ESTERS

被引：0

作者：

BABIEVSKII, KK

FILATOVA, IM

BELIKOV, VM

机构：

[1] Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 04期

关键词：

D O I：

10.1007/BF00923564

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1. It has been shown, for the first time, that geometrical isomerization affects the electrochemical reduction of the conjugated nitroalkenes. 2. The reduction potentials are lower for the E isomers of the esters of α-nitrocinnamic acids than for the companion Z isomers. 3. The E isomers of these esters adsorb more readily on the dropping mercury electrode than do the companion Z isomers. © 1979 Plenum Publishing Corporation.

引用

页码：701 / 704

页数：4