PRECONCENTRATION AND DETERMINATION OF BISMUTH(III) AT A CHEMICALLY MODIFIED ELECTRODE CONTAINING 1-(2-PYRIDYLAZO)-2-NAPHTHOL

被引：27

作者：

DONG, KL ^{[1
]}

KRYGER, L ^{[1
]}

CHRISTENSEN, JK ^{[1
]}

THOMSEN, KN ^{[1
]}

机构：

[1] AARHUS UNIV,DEPT CHEM,LANGELANDSGADE 140,DK-8000 AARHUS,DENMARK

来源：

TALANTA | 1991年 / 38卷 / 01期

关键词：

D O I：

10.1016/0039-9140(91)80015-R

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A chemically modified electrode (CME) containing 1-(2-pyridylazo-2-naphthol is evaluated for its ability to preconcentrate bismuth(III) prior to quantification by voltammetry. The CME approach is shown to be sufficiently sensitive for sub-nanomolar concentrations to be determinable after chemical deposition for 60 sec. Further, when the bismuth is deposited from iodide-containing sulphuric acid media, the discrimination against interference by copper(II) is significantly better than that obtained with conventional stripping analysis. The results obtained for Bi(III) in an NBS reference solution agree well with the recommended value.

引用

页码：101 / 105

页数：5

共 11 条

[1]

[Anonymous], 1985, STRIPPING ANAL PRINC

[2] VOLTAMMETRIC DETERMINATION OF TRACES OF NICKEL(II) AT A CHEMICALLY MODIFIED ELECTRODE BASED ON DIMETHYLGLYOXIME-CONTAINING CARBON PASTE [J].

BALDWIN, RP ;

CHRISTENSEN, JK ;

KRYGER, L .

ANALYTICAL CHEMISTRY, 1986, 58 (08) :1790-1798

[3]

FAULKNER LR, 1984, CHEM ENG NEWS, P28

[4] DETERMINATION OF BISMUTH IN MARINE SAMPLES BY ANODIC-STRIPPING VOLTAMMETRY [J].

FLORENCE, TM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1974, 49 (02) :255-264

[5]

HENZE G, 1986, ELEKTROCHEMISCHE ANA

[6]

MURRAY RW, 1984, ELECTROANAL CHEM, V13, P191

[7] CHEMICALLY MODIFIED ELECTRODES - MOLECULAR DESIGN FOR ELECTROANALYSIS [J].

MURRAY, RW ;

EWING, AG ;

DURST, RA .

ANALYTICAL CHEMISTRY, 1987, 59 (05) :A379-&

[8] CHEMICAL PRECONCENTRATION AND DETERMINATION OF COPPER AT A CHEMICALLY MODIFIED CARBON-PASTE ELECTRODE CONTAINING 2,9-DIMETHYL-1, 10-PHENANTHROLINE [J].

PRABHU, SV ;

BALDWIN, RP ;

KRYGER, L .

ANALYTICAL CHEMISTRY, 1987, 59 (08) :1074-1078

[9]

Stary J., 1964, SOLVENT EXTRACTION M, V1st

[10] PROGRAMMABLE ANALYZER FOR VOLTAMMETRIC AND CHRONOPOTENTIOMETRIC EXPERIMENTS [J].

THOMSEN, KN ;

SKOV, HJ ;

KRYGER, L .

ANALYTICA CHIMICA ACTA, 1989, 219 (01) :105-121

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