PERFLUOROALKYLATIONS AND PERFLUOROOXAALKYLATIONS .2. COPPER MEDIATED CROSS-COUPLING OF SECONDARY PERFLUOROOXAALKYL IODIDES AND ARYL HALIDES

被引：18

作者：

CHEN, GJ ^{[1
]}

CHEN, LS ^{[1
]}

EAPEN, KC ^{[1
]}

机构：

[1] UNIV DAYTON,RES INST,DAYTON,OH 45469

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 65卷 / 1-2期

关键词：

D O I：

10.1016/S0022-1139(00)80474-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first successful application of the copper-mediated cross-coupling reaction using secondary perfluorooxaalkyl iodides and iodoaromatic substrates is described. The yields of the cross-coupled products are optimized by careful choice and control of the experimental conditions. The by-products formed are identified and their probable mode of formation is discussed.

引用

页码：59 / 65

页数：7

共 8 条

[1]

ANKUDINOV AK, 1972, J ORG CHEM USSR, V8, P217

[2] POLYFLUOROALKYLATION OF BROMOHETEROCYCLIC COMPOUNDS VIA PERFLUOROALKYLCOPPER INTERMEDIATES [J].

CHEN, GJ ;

TAMBORSKI, C .

JOURNAL OF FLUORINE CHEMISTRY, 1990, 46 (01) :137-159

[3] POLYFLUOROALKYLATION OF BROMOAROMATIC COMPOUNDS VIA PERFLUOROALKYLCOPPER INTERMEDIATES [J].

CHEN, GJ ;

TAMBORSKI, C .

JOURNAL OF FLUORINE CHEMISTRY, 1989, 43 (02) :207-228

[4] PERFLUOROALKYLATIONS AND PERFLUOROOXAALKYLATIONS .1. BROMOAROMATICS AS SUBSTRATES IN COPPER-MEDIATED CROSS-COUPLING [J].

CHEN, GJ ;

CHEN, LS ;

EAPEN, KC .

JOURNAL OF FLUORINE CHEMISTRY, 1993, 63 (1-2) :113-123

[5] A ROUTE TO FLUOROALKYL-SUBSTITUTED AROMATIC COMPOUNDS INVOLVING FLUOROALKYLCOPPER INTERMEDIATES [J].

MCLOUGHL.VC ;

THROWER, J .

TETRAHEDRON, 1969, 25 (24) :5921-&

[6] THE SYNTHESIS OF PERFLUOROALKYL AND PERFLUOROALKYLETHER SUBSTITUTED BENZILS [J].

PACIOREK, KJL ;

MASUDA, SR ;

SHIH, JG ;

NAKAHARA, JH .

JOURNAL OF FLUORINE CHEMISTRY, 1991, 53 (02) :233-248

[7]

PSARRAS T, 1974, 168 ACS NAT M ATL CI

[8]

VONWERNER K, 1988, Patent No. 295582

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