THERMAL-DECOMPOSITION OF CESIUM-POTASSIUM IODOTHIOCYANATOBISMUTHATES(III)

被引：3

作者：

TUREK, A ^{[1
]}

CYGANSKI, A ^{[1
]}

机构：

[1] TECH UNIV LODZ,INST GEN & ECOL CHEM,PL-90924 LODZ,POLAND

来源：

THERMOCHIMICA ACTA | 1994年 / 241卷

关键词：

D O I：

10.1016/0040-6031(94)87013-6

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

New double complex bismuth salts of the general formula Cs2K[Bi(SCN)(x)I-6-x] where x = 1, 2 and Cs2K[Bi-2(SCN)(y)I-9-y] where y = 5, 6, 7 have been obtained by dissolving Cs[Bi(SCN)(4)] in KI solutions of various concentrations. The mechanism of the thermal decomposition of these compounds has been determined on the basis of thermal curves, chemical and diffractometric analyses of the solid pyrolysis products. The decomposition was found to proceed in three stages.

引用

页码：121 / 130

页数：10

共 8 条

[1] THERMAL-DECOMPOSITION OF CESIUMIODOBISMUTHATES(III) [J].

BOGUSLAWSKA, K ;

CYGANSKI, A ;

KRYSTEK, J .

JOURNAL OF THERMAL ANALYSIS, 1986, 31 (03) :605-610

[2] STUDIES ON THERMAL-DECOMPOSITION OF CESIUM-SODIUM CHLOROTHIOCYANATOBISMUTHATES(III) [J].

CYGANSKI, A ;

TUREK, A .

THERMOCHIMICA ACTA, 1989, 137 (02) :337-352

[3] STUDIES ON THE THERMAL-DECOMPOSITION OF CESIUM SODIUM BROMOTHIOCYANATOBISMUTHATES(III) [J].

CYGANSKI, A ;

TUREK, A .

THERMOCHIMICA ACTA, 1990, 164 :269-283

[4] KINETIC-PARAMETERS OF THERMAL-DECOMPOSITION OF THIOCYANATOBISMUTHATES(III) .2. DOUBLE SALTS [J].

CYGANSKI, A ;

KOBYLECKA, J .

THERMOCHIMICA ACTA, 1991, 178 :321-329

[5]

CYGANSKI A, 1978, POL J CHEM, V52, P2321

[6]

CYGANSKI A, 1965, ROCZN CHEM, V39, P193

[7]

GLUND W, 1926, BER, V59, P1384

[8] STUDIES ON THERMAL-DECOMPOSITION OF CESIUM SODIUM FLUOROTHIOCYANATOBISMUTHATES(III) AND IODOTHIOCYANATOBISMUTHATES(III) [J].

TUREK, A ;

CYGANSKI, A .

THERMOCHIMICA ACTA, 1992, 197 (01) :225-238

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