STEREOCONTROLLED SYNTHESIS OF CALYCULIN-A - CONSTRUCTION OF THE C(15)-C(25) SPIROKETAL UNIT

被引：37

作者：

BARRETT, AGM ^{[1
]}

EDMUNDS, JJ ^{[1
]}

HORITA, K ^{[1
]}

PARKINSON, CJ ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001236

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two concise enantioselective syntheses of the C(15)-C(25) spiroketal unit of calyculin A, using derivatives of allyldiisopinocampheylborane efficiently to control 1,2- and 1,3-diol stereochemistries, are reported.

引用

页码：1236 / 1238

页数：3

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