A general expression is derived for the first-order long-range interaction between atoms with one open shell. An interaction energy decreasing as the inverse fifth power of the distance with a coefficient of 2.0 x 10(-51) erg cm(5) is predicted for the b(3)Sigma(+) state of CO, in harmony with an analysis of experimental predissociation data.
机构:
St Petersburg State Univ, Dept Phys, Oulianovskaya 1, St Petersburg 198504, RussiaSt Petersburg State Univ, Dept Phys, Oulianovskaya 1, St Petersburg 198504, Russia
Zalialiutdinov, T.
Solovyev, D.
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机构:
St Petersburg State Univ, Dept Phys, Oulianovskaya 1, St Petersburg 198504, RussiaSt Petersburg State Univ, Dept Phys, Oulianovskaya 1, St Petersburg 198504, Russia