GENERATION OF SOLUTIONS OF HIGHLY PERSISTENT RADICAL CATIONS BY 4-TOLYLTHALLIUM(III) BIS(TRIFLUOROACETATE) IN 1,1,1,3,3,3-HEXAFLUOROPROPAN-2-OL

被引：35

作者：

EBERSON, L ^{[1
]}

HARTSHORN, MP ^{[1
]}

PERSSON, O ^{[1
]}

机构：

[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 11期

关键词：

D O I：

10.1039/c39950001131

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

4-Tolylthallium(III) bis(trifluoroacetate) acts as a one-electron oxidant toward aromatic substrates in trifluoroacetic acid or 1,1,1,3,3,3-hexafluoropropan-2-ol, the latter solvent giving radical cation solutions of uniquely high persistency at room temperature.

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页码：1131 / 1132

页数：2

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