A REMPI STUDY OF SOLVATION OF SMALL HGN CLUSTERS BY POLAR-MOLECULES

被引：4
|
作者：
DEDONDERLARDEUX, C
JOUVET, C
MARTRENCHARD, S
SOLGADI, D
TRAMER, A
机构：
[1] Laboratoire de Photophysique Moléculaire CNRS, Université de Paris Sud, Orsay
来源：
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS | 1991年 / 20卷 / 1-4期
关键词：
D O I：
10.1007/BF01543941
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Free Hg(n)(DME)m clusters (where DME = dimethyl-ether, n = 1,2,3, m = 1 divided-by 5) formed in a supersonic expansion were studied by the REMPI (Resonance-Enhanced Multi-Photon Ionization) technique. A large decrease of ionization energies due to solvation of Hg(n) clusters is observed. Preliminary results are discussed in terms of different equilibrium configurations of the electronic ground, excited and ionic states of clusters.
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页码：73 / 75
页数：3
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