ABSOLUTE STEREOCHEMISTRY OF ALISAMYCIN

被引：15
|
作者：
HAYASHI, K [1 ]
NAKAGAWA, M [1 ]
FUJITA, T [1 ]
NAKAYAMA, M [1 ]
机构：
[1] UNIV OSAKA PREFECTURE, FAC AGR, DEPT AGR CHEM, SAKAI, OSAKA 593, JAPAN
来源：
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1994年 / 58卷 / 07期
关键词：
D O I：
10.1271/bbb.58.1332
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Alisamycin is a new manumycin group antibiotic. Manumycin group antibiotics have three asymmetric carbons at C4, C5, and C6 in their structures. The absolute structure of alisamycin was determined by the exciton chirality method and CD spectrum of the oxidative product of alisamycin. Configurations of C4, C5, and C6 were assigned to be 4R, 5S, and 6R.
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收藏
页码：1332 / 1333
页数：2
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