Bis[tetrakis(pyridin-2-yl)methane-kappa N-3,N ',N '']cobalt(II) tetrakis(thiocyanato-kappa N)cobaltate(II) methanol monosolvate

被引：3
|
作者：
Tsunezumi, Yuya [1 ]
Matsumoto, Kouzou [2 ]
Hayami, Shinya [3 ]
Fuyuhiro, Akira [4 ]
Kawata, Satoshi [1 ]
机构：
[1] Fukuoka Univ, Fac Sci, Dept Chem, Jonan Ku, Fukuoka 8140180, Japan
[2] Senshu Univ, Inst Nat Sci, Tama Ku, Kawasaki, Kanagawa 2148580, Japan
[3] Kumamoto Univ, Grad Sch Sci & Technol, Dept Chem, Kumamoto 8608555, Japan
[4] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
Data-to-parameter ratio = 17.4; Disorder in solvent or counterion; Mean σ(C-C) = 0.004 Å; R factor = 0.034; Single-crystal X-ray study; T = 100 K; wR factor = 0.071;
D O I：
10.1107/S160053681400289X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Co(C21H16N4) 2][Co(NCS)4]·CH3OH, consists of one [Co{C(py)4}2]2+ complex cation [C(py) 4 = tetrakis(pyridin-2-yl)methane], one [Co(NCS)4] 2- complex anion and a methanol solvent molecule. In the cation, the CoII atom is coordinated by six N atoms of two C(py)4 ligands in a distorted octahedral geometry. In the anion, the CoII atom is coordinated by the N atoms of four NCS- ligands in a distorted tetrahedral geometry. The methanol molecule is disordered and was modelled over three orientations (occupancies 0.8:0.1:0.1). There are two weak hydrogen-bond-like interactions between the methanol solvent molecule and NCS- ligands of the anion [O⋯S = 3.283 (3) and 3.170 (2) Å].
引用
收藏
页码：M96 / +
页数：21
相关论文
共 50 条
  • [11] Dipotassium tetrakis(thiocyanato-kappa S)palladate(II)-(2,2 '-bipyrimidine-kappa N-2(1),N-1 ')bis(thiocyanato-kappa S)palladium(II) (1/ 2)
    Ha, Kwang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M616 - +
  • [12] Crystal structure of [2-({4-[2,6-bis(pyridin-2-yl) pyridin-4-yl] phenyl}(methyl)amino) ethanol-kappa(3) N, N ', N '''] bis(thiocyanato-kappa N) zinc N, N-dimethylformamide monosolvate
    Wang, Shi-Chao
    Pan, Rou-Chen
    Song, Wan-Ying
    Li, Sheng-Li
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M347 - +
  • [13] [(4-Methylbenzyl)bis(pyridin-2-ylmethyl)amine-kappa N-3,N ',N '']bis(thiocyanato-kappa S)-copper(II) dichloromethane hemisolvate
    Qi, Yan
    Li, Yang
    Ma, Zheng-Ping
    Chen, Qiu-Yun
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M468 - +
  • [14] Poly[[bis[mu(2)-1,2-bis(pyridin-4-yl) ethene-kappa N-2:N '] bis(thiocyanato-kappa N) cobalt(II)]1,2-bis(pyridin-4-yl) ethene monosolvate dihydrate]
    Woehlert, Susanne
    Jess, Inke
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M482 - +
  • [15] [mu-1,2,3,4-Tetrakis(pyridin-4-yl)butane kappa(2) N-1 :N-4]bis[trimethyl(thiocyanato-kappa N)tin(IV)]
    Najafi, Ezzatollah
    Amini, Mostafa M.
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1550 - +
  • [16] A triclinic polymorph of poly[[bis[mu-1,2-bis(pyridin-4-yl)ethene-kappa N-2:N ']-bis(thiocyanato-kappa N)cobalt(II)] 1,2-bis(pyridin-4-yl)ethene monosolvate]
    Mohlert, Susanne
    Jess, Lnke
    Nather, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M733 - +
  • [17] Crystal structures of bis[4-(dimethylamino)-pyridinium] tetrakis(thiocyanato-kappa N)manganate(II) and tris[4-(dimethylamino) pyridinium]pentakis-(thiocyanato-kappa N)manganate(II)
    Neumann, Tristan
    Jess, Inke
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 15 - +
  • [18] Poly[tris(mu-4,4 '-bipyridine-kappa N-2:N ')bis(dimethyl sulfoxide-kappa O)tetrakis(thiocyanato-kappa N)dicobalt(II)]
    Kaenket, Surasak
    Phuengphai, Pongthipun
    Pakawatchai, Chaveng
    Youngme, Sujittra
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M265 - +
  • [19] Crystal structure of bis(2,2 '-bipyridine-kappa(2) N, N ')bis(thiocyanato-kappa N) manganese(II) 2,2 '-bipyridine monosolvate
    Suckert, Stefan
    Jess, Inke
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M3 - +
  • [20] Diaquabis(nicotinamide-kappa N-1) bis(thiocyanato-kappa N) nickel(II)
    Pandey, Deepanjali
    Narvi, Shahid S.
    Mehrotra, Gopal K.
    Butcher, Raymond J.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M183 - +
12345