SYNTHESIS OF SOME TRANSITION-METAL COMPLEXES DERIVED FROM (1-CARBONYLMETHYL-1H-BENZOTRIAZOLE)-4-PHENYL-3-THIOSEMICARBAZIDE

被引：0

作者：

ZHANG, YL ^{[1
]}

WU, H ^{[1
]}

XU, PF ^{[1
]}

WUSZ ^{[1
]}

机构：

[1] LANZHOU UNIV,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1994年 / 24卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of the type (ML . X H2O)n where M = Mn (II), Ni(II), Zn (II), Cd(II), Pb(II), L = (1-carbonylmethyl-1H-benzotriazole)-1-phenyl-3-thiosemicarbazide (BPTSH2), X = 0, 1, 2 and n = degree of polymerization have been synthesized and characterized by elemental and thermal analyses along with IR and H-1 NMR spectra. Infrared spectra are consistent with tetradentate coordination involving the carbonyl and thiocarbonyl groups in conjunction with the adjacent nitrogen atoms (C = N groups) with each ligand binding to two metal centers. The result is proposed to be polymers that grow through consecutive ligand-metal linkages.

引用

页码：1479 / 1485

页数：7

共 13 条

[1] LIGATIONAL BEHAVIOR OF A TETRADENTATE NONS DONOR LIGAND TOWARDS SOME TRANSITION-METAL IONS [J].