catena-Poly[[(2-{[2-(dimethylammonio)-ethyl]iminomethyl}pyridine-kappa N-2, N')bis-(thiocyanato-kappa N)manganese(II)]-mu-thiocyanato-kappa N-2:S]

被引：0
作者：
Wang, Jun [1 ]
Zhu, Wubiao [1 ]
Li, Jichang [1 ]
机构：
[1] Zhongshan Polytechn, Zhongshan 528404, Guangdong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 17.4; mean σ(C-C) = 0.005 Å; R factor = 0.043; single-crystal X-ray study; T = 296 K; wR factor = 0.098;
D O I：
10.1107/S1600536812032874
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title one-dimensional coordination polymer, [Mn(NCS)(3)(C10H16N3)](n), the Mn-II atom is coordinated by an N, N'-bidentate Schiff base and four thiocyanate ligands in a distorted octahedral N5S geometry. Bridging thiocyanate ligands interconnect adjacent [Mn(NCS)(2)(C10H16N3)] units, giving rise to helical chains extending along the b axis. The chains are further linked through N-H center dot center dot center dot S hydrogen bonds, leading to a three-dimensional supramolecular network.
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页码：M1131 / +
页数：8
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